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- W2057413426 abstract "A mixed-valence complex of vanadium-(IV) and -(V). Na[V2O3(DL-salser)2]·5H2O (salser =N-salicylideneserinate) has been isolated from solutions containing oxovanadium(IV), DL-serine and salicylaldehyde. Its structure has been determined by X-ray diffraction analysis: space group P21/c, a= 12.845(5), b= 16.615(4), c= 13.072(0)Å, β= 103.53(9)°, Z= 4 and R= 0.0494 for 2860 observed reflections. The V2O33+ unit in this complex has a V–O–V angle smaller than the usual values and each complex ion contains a D- and a L-serine residue. Each sodium ion is surrounded by seven oxygen atoms in a distorted pentagonal-bipyramidal geometry. The magnetic moment and thermogravimetric analysis are also in accord with the structure." @default.
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- W2057413426 date "1992-01-01" @default.
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- W2057413426 title "Salicylideneserinato complexes of vanadium. Crystal structure of the sodium salt of a complex of vanadium-(IV) and -(V)" @default.
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- W2057413426 doi "https://doi.org/10.1039/dt9920001745" @default.
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