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- W2057445230 abstract "(GeTe4)100−xAgx and (GeTe4)100−x(AgI)x glasses were prepared by a melting-quenching method. The glass electrical conductivity was investigated by both electrochemical impedance spectroscopy at different temperatures from 283 K to 333 K and four-probe method at room temperature (293 K). Meanwhile, as a major factor determining the electrical conductivity of a solid, optical band gap was also studied. By comparing the electrical conductivity values and glass optical band gap evolution, it was found that (GeTe4)100−xAgx glasses are mainly electronic conductive. On the other hand, the electrical conductivities of (GeTe4)100−x(AgI)x glasses firstly show a monotonic decrease by increasing AgI up to 15 mol.%, and then an increase when the AgI content is higher than 15 mol.%. The activation energy Ea and the pre-exponential factor σ0 show apparent turning point when AgI content is 15 mol.%, signifying a conductivity mechanism change. In this paper, correlations between the conductivity and hypothetical structures in (GeTe4)100−xAgx and (GeTe4)100−x(AgI)x glasses are done and the importance of the Ag role is underlined." @default.
- W2057445230 created "2016-06-24" @default.
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- W2057445230 date "2015-08-01" @default.
- W2057445230 modified "2023-09-27" @default.
- W2057445230 title "Electrical and optical investigations in Te–Ge–Ag and Te–Ge–AgI chalcogenide glasses" @default.
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- W2057445230 doi "https://doi.org/10.1016/j.jallcom.2015.03.138" @default.
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