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- W2057453896 abstract "Infrared spectra oftrans-monodeutero-diimide, HNND, have been recorded between 760 and 3250 cm−1at a resolution of ca. 0.005–0.007 cm−1, from which the fundamental bands ν1, ν4, ν5, and ν6of this isotope have been studied. A detailed analysis of thea,b-Coriolis interacting band system ν5, ν6near 1100 cm−1is presented. The ν4band at 1475 cm−1has been analyzed by a model includingc-Coriolis and ΔKa= ±2 vibrational resonance with the close lying ν3band at 1538 cm−1. Only 18 transitions in ν3which obtain their intensity through interaction with the ν4band have been assigned. Together with the observed perturbation effects in ν4they provide valuable information for the ν3level, too. In the ν1band around 3110 cm−1numerous local crossings due to vibrational andc-Coriolis interactions with the unobserved binary combinations 2ν3, ν3+ ν4, and 2ν4have been identified. The present analyses yield a number of spectroscopic constants for the ν1, ν3, ν4, ν5, and ν6levels and various interaction constants. From a simultaneous ground state combination difference analysis of the four observed bands the following ground state rotational constants are obtained:A0= 7.384213(4) cm−1,B0= 1.1959457(6) cm−1, andC0= 1.0255827(6) cm−1." @default.
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- W2057453896 date "1997-01-01" @default.
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- W2057453896 title "High-Resolution Infrared Study oftrans-Monodeutero-diimide, HNND" @default.
- W2057453896 doi "https://doi.org/10.1006/jmsp.1996.7149" @default.
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