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- W2057466646 abstract "This paper discusses the nature of the products formed from the reaction of 2-pyridinecarboxaldehyde and methylamine. The synthesized products manifest themselves in two distinct forms, one an oil and the other crystalline, which have identical chemical properties but differ dramatically in their spectroscopic parameters. A novel trimeric structure, the hexahydro-s-triazine, is suggested for the crystalline form, while the oil appears to be the monomeric N-methyl pyridine-2-carboxaldimine. IR, UV–vis, Raman and NMR spectroscopies are used to validate the proposed structures. The conversion of the trimeric crystalline form to the monomeric oil form, is acid-catalyzed and occurs rapidly." @default.
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- W2057466646 date "1999-08-01" @default.
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- W2057466646 title "The acid catalyzed conversion of 1,3,5-trimethyl-2,4,6-tris(2-pyridyl)hexahydro-s-triazine into the asymmetric monomer, N-methylpyridine-2-carboxaldimine" @default.
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- W2057466646 doi "https://doi.org/10.1016/s0924-2031(99)00036-3" @default.
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