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• W2057491165 abstract "A novel series of Cu(II) complexes of azo rhodanine derivatives (HLn) have been prepared and characterized by thermal analysis, spectral studies (IR, mass, UV–Vis, ESR) and magnetic measurements. IR spectra suggest that the HLn acts as a bidentate ligands coordinating via (NN) and deprotonated enolized carbonyl oxygen (–C–O–). ESR spectra of the Cu(II) complexes show dx2−y2 as a ground state, suggesting tetrahedral distorted or square planar geometries around Cu(II) center. The X-ray diffraction (XRD) patterns powder forms of Cu(II) complexes shows many diffraction peaks which indicates the polycrystalline phase. Thermal properties and decomposition kinetics of compounds are investigated. The thermodynamic parameters and evaluation of kinetic parameters (Ea, ΔS∗, ΔH∗ and ΔG∗) of thermal decomposition stages have been evaluated using Coats–Redfern and Horowitz–Metzger methods. Cu(II) complexes are screened for their biological activity against bacterial and fungal species. The Cu(II) complexes showed antimicrobial activities against Staphylococcus aureus and Penicillium italicum." @default.
• W2057491165 created "2016-06-24" @default.
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• W2057491165 date "2015-05-01" @default.
• W2057491165 modified "2023-10-17" @default.
• W2057491165 title "Thermal, spectroscopic studies and hydrogen bonding in supramolecular assembly of azo rhodanine complexes" @default.
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• W2057491165 doi "https://doi.org/10.1016/j.ica.2015.02.031" @default.
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