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- W2057499146 abstract "Sulphides have been oxidised with an anhydrous solution of hydrogen peroxide in tertiary butyl alcohol containing a catalytic amount of vanadium pentoxide to give sulphones and sulphoxides. This method was very useful for the partial oxidation of labiles sulphides (e.g.α-chloro-sulphides, and α-acetoxy-sulphide, and thiiran) to sulphoxides of high purity. A reported preparation of 2-hydroxymethylthiiran and the corresponding sulphone has been shown to yield instead 3-hydroxytheitan and 3-hydroxythietan 1,1-dioxide." @default.
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- W2057499146 date "1969-01-01" @default.
- W2057499146 modified "2023-10-16" @default.
- W2057499146 title "The vanadium pentoxide-catalysed oxidation of thio-compounds with hydrogen peroxide" @default.
- W2057499146 doi "https://doi.org/10.1039/j39690002334" @default.
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