FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2057536911> ?p ?o ?g. }

• W2057536911 endingPage "2220" @default.
• W2057536911 startingPage "2216" @default.
• W2057536911 abstract "The generation of heavier double-bond systems without by- or side-product formation is of considerable importance for their application in synthesis. Peripheral functional groups in such alkene homologues are promising in this regard owing to their inherent mobility. Depending on the steric demand of the N-alkyl substituent R, the reaction of disilenide Ar2SiSi(Ar)Li (Ar=2,4,6-iPr3C6H2) with ClP(NR2)2 either affords the phosphinodisilene Ar2SiSi(Ar)P(NR2)2 (for R=iPr) or P-amino functionalized phosphasilenes Ar2(R2N)SiSi(Ar)P(NR2) (for R=Et, Me) by 1,3-migration of one of the amino groups. In case of R=Me, upon addition of one equivalent of tert-butylisonitrile a second amino group shift occurs to yield the 1-aza-3-phosphaallene Ar2(R2N)SiSi(NR2)(Ar)PCNtBu with pronounced ylidic character. All new compounds were fully characterized by multinuclear NMR spectroscopy as well as single-crystal X-ray diffraction and DFT calculations in selected cases." @default.
• W2057536911 created "2016-06-24" @default.
• W2057536911 creator A5010874134 @default.
• W2057536911 creator A5033248687 @default.
• W2057536911 creator A5043209428 @default.
• W2057536911 creator A5051854568 @default.
• W2057536911 creator A5072731419 @default.
• W2057536911 creator A5083296313 @default.
• W2057536911 date "2014-01-23" @default.
• W2057536911 modified "2023-10-02" @default.
• W2057536911 title "From Disilene (SiSi) to Phosphasilene (SiP) and Phosphacumulene (PCN)" @default.
• W2057536911 cites W1967312380 @default.
• W2057536911 cites W1968497326 @default.
• W2057536911 cites W1971428915 @default.
• W2057536911 cites W1973735850 @default.
• W2057536911 cites W1975892908 @default.
• W2057536911 cites W1992142988 @default.
• W2057536911 cites W1992744465 @default.
• W2057536911 cites W1997452448 @default.
• W2057536911 cites W2002728069 @default.
• W2057536911 cites W2004253187 @default.
• W2057536911 cites W2004288527 @default.
• W2057536911 cites W2005148229 @default.
• W2057536911 cites W2008899903 @default.
• W2057536911 cites W2012326238 @default.
• W2057536911 cites W2014555226 @default.
• W2057536911 cites W2017813412 @default.
• W2057536911 cites W2029168981 @default.
• W2057536911 cites W2029860592 @default.
• W2057536911 cites W2030722913 @default.
• W2057536911 cites W2033735656 @default.
• W2057536911 cites W2034900040 @default.
• W2057536911 cites W2037078338 @default.
• W2057536911 cites W2037281151 @default.
• W2057536911 cites W2044761483 @default.
• W2057536911 cites W2045662986 @default.
• W2057536911 cites W2047561297 @default.
• W2057536911 cites W2047950596 @default.
• W2057536911 cites W2052568638 @default.
• W2057536911 cites W2065615159 @default.
• W2057536911 cites W2069329659 @default.
• W2057536911 cites W2071793500 @default.
• W2057536911 cites W2075257456 @default.
• W2057536911 cites W2084403181 @default.
• W2057536911 cites W2085088193 @default.
• W2057536911 cites W2087719260 @default.
• W2057536911 cites W2091511348 @default.
• W2057536911 cites W2091873670 @default.
• W2057536911 cites W2094683869 @default.
• W2057536911 cites W2095512364 @default.
• W2057536911 cites W2105914266 @default.
• W2057536911 cites W2108239226 @default.
• W2057536911 cites W2111721748 @default.
• W2057536911 cites W2111835934 @default.
• W2057536911 cites W2126645515 @default.
• W2057536911 cites W2131700384 @default.
• W2057536911 cites W2133936891 @default.
• W2057536911 cites W2137350008 @default.
• W2057536911 cites W2142340513 @default.
• W2057536911 cites W2142987946 @default.
• W2057536911 cites W2147867735 @default.
• W2057536911 cites W2147901429 @default.
• W2057536911 cites W2152800284 @default.
• W2057536911 cites W2155076757 @default.
• W2057536911 cites W2162995917 @default.
• W2057536911 cites W2169218162 @default.
• W2057536911 cites W2318604445 @default.
• W2057536911 cites W2319616274 @default.
• W2057536911 cites W2327387584 @default.
• W2057536911 cites W2949383970 @default.
• W2057536911 cites W2949647599 @default.
• W2057536911 cites W2952049703 @default.
• W2057536911 cites W4206278248 @default.
• W2057536911 cites W4230927280 @default.
• W2057536911 cites W4236017535 @default.
• W2057536911 doi "https://doi.org/10.1002/anie.201308525" @default.
• W2057536911 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24458444" @default.
• W2057536911 hasPublicationYear "2014" @default.
• W2057536911 type Work @default.
• W2057536911 sameAs 2057536911 @default.
• W2057536911 citedByCount "58" @default.
• W2057536911 countsByYear W20575369112014 @default.
• W2057536911 countsByYear W20575369112015 @default.
• W2057536911 countsByYear W20575369112016 @default.
• W2057536911 countsByYear W20575369112017 @default.
• W2057536911 countsByYear W20575369112018 @default.
• W2057536911 countsByYear W20575369112019 @default.
• W2057536911 countsByYear W20575369112020 @default.
• W2057536911 countsByYear W20575369112021 @default.
• W2057536911 countsByYear W20575369112022 @default.
• W2057536911 countsByYear W20575369112023 @default.
• W2057536911 crossrefType "journal-article" @default.
• W2057536911 hasAuthorship W2057536911A5010874134 @default.
• W2057536911 hasAuthorship W2057536911A5033248687 @default.
• W2057536911 hasAuthorship W2057536911A5043209428 @default.
• W2057536911 hasAuthorship W2057536911A5051854568 @default.
• W2057536911 hasAuthorship W2057536911A5072731419 @default.
• W2057536911 hasAuthorship W2057536911A5083296313 @default.

• next