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• W2057555813 abstract "The ligands 4-methylthio-6-phenyl-2,2'-bipyridine (1) and the corresponding sulfoxide (2) and sulfone (3) have been synthesized and characterized in solution, and in the solid state by single crystal X-ray diffraction. Compounds 2 and 3 crystallize in the same space group (C2/c) with similar unit cell parameters; a small increase in the unit cell volume allows for the presence of the extra oxygen atom in 3. The sulfoxide and sulfone groups adopt conformations that permit intramolecular O···HC(aryl) hydrogen bonds. The complexes [Ir(ppy)(2)L][PF(6)] with L = 1, 2 or 3 have been prepared and characterized. The asymmetric sulfur atom in ligand 2 gives rise to pairs of diastereoisomers of the complex which can be distinguished in the (1)H and (13)C NMR spectra. In solution, exchange of [PF(6)](-) by [Δ-TRISPHAT](-) gives rise to four diastereoisomers and we observed good dispersion of (1)H NMR resonances, especially for those assigned to protons close to the asymmetric sulfur atom. A single crystal X-ray diffraction study of 2{[Ir(ppy)(2)(3)][PF(6)]}·CHCl(3)·3H(2)O reveals that the complex crystallizes in the chiral space group P2(1)2(1)2(1), the asymmetric unit containing crystallographically independent Δ- and Λ-[Ir(ppy)(2)(3)](+) cations. This provides a rare example of a so-called kryptoracemate in the solid state. In MeCN solution, [Ir(ppy)(2)(1)][PF(6)], [Ir(ppy)(2)(2)][PF(6)] and [Ir(ppy)(2)(3)][PF(6)] are weakly emissive (λ(em) = 600, 647 and 672 nm, respectively) and preliminary studies of the electroluminescent properties of [Ir(ppy)(2)(2)][PF(6)] indicate that the complexes are not suitable candidates for LECs." @default.
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• W2057555813 date "2012-01-01" @default.
• W2057555813 modified "2023-09-26" @default.
• W2057555813 title "Stereochemistry controlled by an asymmetric sulfur atom, and a rare example of a kryptoracemate" @default.
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• W2057555813 doi "https://doi.org/10.1039/c2dt30892d" @default.
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• W2057555813 hasPublicationYear "2012" @default.
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