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• W2057602795 abstract "This work describes the study of underpotential deposition (upd) of Pb on polycrystalline platinum in 0.2M HClO4 solutions using cyclic voltammetry and rotating ring-disk electrode techniques. In such conditions, a full monolayer of upd Pb corresponds to a coverage of 0.41. The adsorption of lead inhibits the adsorption of hydrogen in a non-selective way. This behaviour was explained through the comparison between the radius of the ad-atom and the substrate. It was calculated that each Pb ad-atom occupies two sites in the surface. Additionally it is shown that the presence of upd Pb significantly inhibits the oxygen reduction reaction. This effect associated to the formation of H2O2 as the final product, instead of H2O." @default.
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• W2057602795 date "1994-12-01" @default.
• W2057602795 modified "2023-10-18" @default.
• W2057602795 title "Underpotential deposition of lead on polycrystalline platinum and its influence on the oxygen reduction reaction" @default.
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• W2057602795 doi "https://doi.org/10.1016/0013-4686(94)00256-8" @default.
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