FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2057633040> ?p ?o ?g. }

• W2057633040 endingPage "1369" @default.
• W2057633040 startingPage "1359" @default.
• W2057633040 abstract "Abstract This report describes the electrochemical behavior of a family of “core‐shell” electrocatalysts consisting of a carbon nitride (CN) “shell” matrix and a “core” of conducting carbon nanoparticles (NPs). The CN “shell” matrix embeds PdCoNi alloy NPs and covers homogeneously the carbon “core”. The chemical composition of the materials is determined by inductively‐coupled plasma atomic emission spectroscopy (ICP‐AES) and microanalysis; the structure is studied by powder X‐ray diffraction (powder XRD); the morphology is investigated by high‐resolution transmission electron microscopy (HR‐TEM). The surface activity and structure are probed by CO stripping. The oxygen reduction reaction (ORR) kinetics, reaction mechanism, and tolerance towards contamination from chloride anions are evaluated by cyclic voltammetry with the thin‐film rotating ring‐disk electrode (CV‐TF‐RRDE) method. The effect of N concentration in the matrix (which forms “coordination nests” for the Pd‐based alloy NPs bearing the active sites) on the ORR performance of the electrocatalysts is described. Results show that N atoms: 1) influence the evolution of the structure of the materials during the preparation processes, and 2) interact with alloy NPs, affecting the bifunctional and electronic ORR mechanisms of active sites and the adsorption/desorption processes of oxygen molecules and contaminants. Finally, the best PdCoNi electrocatalyst shows a higher surface activity in the ORR at 0.9 V vs. RHE with respect to the Pt‐based reference (388 μA cm Pd ‐2 vs. 153 μA cm Pt ‐2 )." @default.
• W2057633040 created "2016-06-24" @default.
• W2057633040 creator A5013596615 @default.
• W2057633040 creator A5026503413 @default.
• W2057633040 creator A5033028536 @default.
• W2057633040 creator A5042438267 @default.
• W2057633040 creator A5066909367 @default.
• W2057633040 creator A5075850519 @default.
• W2057633040 creator A5080902862 @default.
• W2057633040 date "2014-08-05" @default.
• W2057633040 modified "2023-10-12" @default.
• W2057633040 title "Interplay between Nitrogen Concentration, Structure, Morphology, and Electrochemical Performance of PdCoNi “Core-Shell” Carbon Nitride Electrocatalysts for the Oxygen Reduction Reaction" @default.
• W2057633040 cites W1532687164 @default.
• W2057633040 cites W1970996323 @default.
• W2057633040 cites W1972034979 @default.
• W2057633040 cites W1974605340 @default.
• W2057633040 cites W1977863466 @default.
• W2057633040 cites W1978322412 @default.
• W2057633040 cites W1979613835 @default.
• W2057633040 cites W1985478504 @default.
• W2057633040 cites W1989580808 @default.
• W2057633040 cites W1997755871 @default.
• W2057633040 cites W2003107392 @default.
• W2057633040 cites W2007045347 @default.
• W2057633040 cites W2007293350 @default.
• W2057633040 cites W2008362086 @default.
• W2057633040 cites W2012219447 @default.
• W2057633040 cites W2021202770 @default.
• W2057633040 cites W2023758012 @default.
• W2057633040 cites W2028785773 @default.
• W2057633040 cites W2031302556 @default.
• W2057633040 cites W2033930164 @default.
• W2057633040 cites W2036173226 @default.
• W2057633040 cites W2040698930 @default.
• W2057633040 cites W2048624014 @default.
• W2057633040 cites W2049635300 @default.
• W2057633040 cites W2058501819 @default.
• W2057633040 cites W2061561556 @default.
• W2057633040 cites W2064188318 @default.
• W2057633040 cites W2067126321 @default.
• W2057633040 cites W2068740451 @default.
• W2057633040 cites W2074207002 @default.
• W2057633040 cites W2078853455 @default.
• W2057633040 cites W2089115060 @default.
• W2057633040 cites W2090399819 @default.
• W2057633040 cites W2090663909 @default.
• W2057633040 cites W2092903091 @default.
• W2057633040 cites W2095252998 @default.
• W2057633040 cites W2136125985 @default.
• W2057633040 cites W2142259364 @default.
• W2057633040 cites W2154241283 @default.
• W2057633040 cites W2164008457 @default.
• W2057633040 cites W2167381077 @default.
• W2057633040 cites W2331285314 @default.
• W2057633040 cites W2952557970 @default.
• W2057633040 doi "https://doi.org/10.1002/celc.201402041" @default.
• W2057633040 hasPublicationYear "2014" @default.
• W2057633040 type Work @default.
• W2057633040 sameAs 2057633040 @default.
• W2057633040 citedByCount "87" @default.
• W2057633040 countsByYear W20576330402014 @default.
• W2057633040 countsByYear W20576330402015 @default.
• W2057633040 countsByYear W20576330402016 @default.
• W2057633040 countsByYear W20576330402017 @default.
• W2057633040 countsByYear W20576330402018 @default.
• W2057633040 countsByYear W20576330402019 @default.
• W2057633040 countsByYear W20576330402020 @default.
• W2057633040 countsByYear W20576330402021 @default.
• W2057633040 countsByYear W20576330402022 @default.
• W2057633040 countsByYear W20576330402023 @default.
• W2057633040 crossrefType "journal-article" @default.
• W2057633040 hasAuthorship W2057633040A5013596615 @default.
• W2057633040 hasAuthorship W2057633040A5026503413 @default.
• W2057633040 hasAuthorship W2057633040A5033028536 @default.
• W2057633040 hasAuthorship W2057633040A5042438267 @default.
• W2057633040 hasAuthorship W2057633040A5066909367 @default.
• W2057633040 hasAuthorship W2057633040A5075850519 @default.
• W2057633040 hasAuthorship W2057633040A5080902862 @default.
• W2057633040 hasBestOaLocation W20576330402 @default.
• W2057633040 hasConcept C104779481 @default.
• W2057633040 hasConcept C127413603 @default.
• W2057633040 hasConcept C140205800 @default.
• W2057633040 hasConcept C146088050 @default.
• W2057633040 hasConcept C147789679 @default.
• W2057633040 hasConcept C159985019 @default.
• W2057633040 hasConcept C161790260 @default.
• W2057633040 hasConcept C171250308 @default.
• W2057633040 hasConcept C17525397 @default.
• W2057633040 hasConcept C178790620 @default.
• W2057633040 hasConcept C179104552 @default.
• W2057633040 hasConcept C185592680 @default.
• W2057633040 hasConcept C192562407 @default.
• W2057633040 hasConcept C194760766 @default.
• W2057633040 hasConcept C2777869211 @default.
• W2057633040 hasConcept C2779227376 @default.
• W2057633040 hasConcept C2780443040 @default.
• W2057633040 hasConcept C33989665 @default.
• W2057633040 hasConcept C42360764 @default.

• next