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• W2057642781 startingPage "2328" @default.
• W2057642781 abstract "Infrared spectra of hydrated hydronium ions weakly bound to an H2 molecule, specifically H7O+3 ⋅H2 and H9O+4 ⋅H2, have been observed. Mass‐selected parent ions, trapped in a radio frequency ion trap, are excited by a tunable infrared laser; following absorption, the complex predissociates with loss of the H2, and the resulting fragment ions are detected. Spectra have been taken from 3000 to 4000 cm−1, with a resolution of 1.2 cm−1. They are compared to recent theoretical and experimental spectra of the hydronium ion hydrates alone. Binding an H2 molecule to these clusters should only weakly perturb their vibrations; if so, our spectra should be similar to spectra of the hydrated hydronium ions H7O+3 and H9O+4." @default.
• W2057642781 created "2016-06-24" @default.
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• W2057642781 date "1986-08-15" @default.
• W2057642781 modified "2023-10-11" @default.
• W2057642781 title "Infrared spectra of the cluster ions H₇O⁺₃⋅H₂ and H₉O⁺₄⋅H₂" @default.
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• W2057642781 doi "https://doi.org/10.1063/1.451079" @default.
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