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• W2057643451 endingPage "1394" @default.
• W2057643451 startingPage "1394" @default.
• W2057643451 abstract "Fulleroids, obtained from the 1,3-dipolar cycloaddition of fullerene with a diazoalkane, have a [5,6]-open methylene bridge and two highly twisted bridgehead double bonds. The [H,H]- and [H,CN]-substituted fulleroids were found to display significantly enhanced and regioselective Diels–Alder addition as compared with the [6,6] closed methanofullerene and C60 with 2,3-dimethyl-1,3-butadiene, but reduced and nonregioselective addition with cyclopentadiene. NMR analysis of the 1 : 1 adduct and quantum calculations indicated that the high reactivity and the regioselective addition are due to π-orbital misalignment at the bridgehead double bond." @default.
• W2057643451 created "2016-06-24" @default.
• W2057643451 creator A5017595263 @default.
• W2057643451 creator A5064416891 @default.
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• W2057643451 date "2010-01-01" @default.
• W2057643451 modified "2023-09-23" @default.
• W2057643451 title "Kinetics and regioselectivity in the Diels–Alder reaction of fulleroids vs. methanofullerene and C60" @default.
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• W2057643451 doi "https://doi.org/10.1039/b918005b" @default.
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