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- W2057648889 abstract "A new surface phase is found in liquid normal-alkanes. X-ray and surface tension measurements show the formation of a crystalline monolayer on the surface of the liquid at temperatures up to 3°C above the bulk solidification temperature, Tf. The molecules in the monolayer are hexagonally packed and oriented normal to the surface. A single solid monolayer persists down to Tf, thus exhibiting a very limited partial wetting. The new surface phase is obtained only for chain lengths 14<n⩽50. Its vanishing for n⩽14 is interpreted as a possible transition from surface freezing to surface melting behaviour. The measurements are satisfactory accounted for within a simple theory based on surface energy cosiderations." @default.
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- W2057648889 date "1993-11-01" @default.
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- W2057648889 title "A new surface phase in liquid normal-alkanes" @default.
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- W2057648889 doi "https://doi.org/10.1016/0378-4371(93)90583-p" @default.
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