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• W2057689957 abstract "With the strong-field scheme and trigonal bases, by diagonalizing the complete d3 energy matrix in a trigonally distorted cubic-field, the energy spectra and wavefunctions of YAl3(BO3)4:Cr3+ have been calculated. The rates of change of levels with respect to various parameters and the contributions to levels from various parameters are calculated, and the physical origins of various levels or splittings have been clearly and quantitatively shown. By using the wavefunctions obtained from diagonalizing the complete energy matrix, the g factors of the ground state of YAl3(BO3)4:Cr3+ have been evaluated. The calculated results are in good agreement with the optical-spectral and EPR experimental data. It is demonstrated that the bonding between Cr3+ and ligands (O2−) is ionic." @default.
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• W2057689957 date "2006-06-01" @default.
• W2057689957 modified "2023-09-25" @default.
• W2057689957 title "Theoretical Studies of Energy Spectra and <i>g</i> Factors of Cr ³⁺ -Doped YAl ₃ (BO ₃ ) ₄" @default.
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• W2057689957 doi "https://doi.org/10.1088/0253-6102/45/6/031" @default.
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