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- W2057692905 abstract "The double-bond and cis-trans isomerizations of n-butenes, n-pentenes, and n-hexenes on a series of solid acids at 150 °C have been studied by means of microreactor-GLC techniques. Various acidic catalysts were found to display different selectivities with respect to double-bond shift and cis-trans isomerization. Upon double-bond shift, cis-olefins normally are formed in preference over their trans-isomers, an exception being the preferred formation of trans-2-hexene from cis-3-hexene. In those reactions where cis-olefins are preferentially formed, trans-olefins are also formed as true primary products of double-bond shift. It is concluded that double-bond shift largely occurs by way of a concerted reaction." @default.
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- W2057692905 date "1962-03-01" @default.
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- W2057692905 title "The mechanism of double-bond isomerization of olefins on solid acids" @default.
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- W2057692905 doi "https://doi.org/10.1016/0021-9517(62)90005-2" @default.
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