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- W2057703655 abstract "X-irradiation of a single crystal of thiophosphate O,O,O-triester of methyl β-D-ribopyranoside at 77 K produces a σ phosphoranyl radical anion (2) by electron capture among secondary radicals resulting from bond scission. The ESR parameters of (2) in correlation with the x-ray analysis of its precursor establish a TBP structure with the unpaired electron in apical position. The results suggest that in irradiated nucleic acid polymers, electrons can be trapped by phosphorus giving rise to a phosphorus-centered radical which subsequently induces bond break by α or β scission generating thermodynamically more stable sugar and base radicals." @default.
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- W2057703655 date "1982-03-01" @default.
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- W2057703655 title "Single crystal ESR study of x-irradiated thiophosphate O,O,O-triester of methyl β-<i>D</i>-ribopyranoside: Electron capture by the thiophosphate moiety" @default.
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- W2057703655 doi "https://doi.org/10.1063/1.443313" @default.
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