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- W2057720092 abstract "Experimental results evidenced the chemical structure of phosphonium salts to be essential in the process of corrosion inhibition for zinc and iron metals in the presence of Ph4−yP+Ry, X− compounds (0 ≤ y ≤ 4) in an acid medium. Several steps are involved in a complex mechanism, each of which being enhanced or strongly reduced by altering the substitutions of the phosphorus atom. Aromaticity and steric hindrance of the radicals are prevailing factors. The inhibition efficiency structure correlation is based on an analytical and electrochemical study of the inhibition process. Inhibierung der Metallkorrosion in sauren Medien mit Hilfe der Phosphoniumsalze: Zink und Eisen Aufgrund von experimentellen Ergebnissen ist die chemische Struktur der Phosphoniumsalze wesentlich für die Inhibierung der Korrosion von Zink und Eisen in Säuren; verwendet werden dabei Salze des Typs Ph4−yP+Ry, X− für 0 ≤ y ≤ 4. Der komplexe Inhibierungsmechanismus umfaßt mehrere Schritte, von denen jeder einzelne durch die Veränderung der Substituenten am Phosphoratom stark beschleunigt oder verzögert werden kann. Vorwiegend handelt es sich bei den Strukturfaktoren um den aromatischen Charakter der Verbindungen und um sterische Behinderungen. Die Beziehung zwischen Hemmwert und Konstitution beruht auf einer analytischen und elektrochemischen Untersuchung des Inhibierungsvorgangs." @default.
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- W2057720092 date "1983-11-01" @default.
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- W2057720092 title "Inhibition of Metallic corrosion in an acid medium by means of phosphonium salts: Zinc and iron" @default.
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- W2057720092 doi "https://doi.org/10.1002/maco.19830341105" @default.
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