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- W2057745729 abstract "Abstract The phase transitions occurring in the perovskite type two-dimensional molecular composite NH3-(CH2)4-NH3 CuCl4, have been studied by D. S. C., X-ray diffraction, EPR and magnetic susceptibility measurements. This compound exhibits a reversible first-order structural phase transition at T = 325 K, between two monoclinic phases III (P2/c) and II (P21/c). This transition is mainly characterized by an important increase of the interlayer metallic distance (+0.137nm) and a shortening of the intralayer metallic distance Cu-Cu (−0.017 nm). These features are due to a conformational change of the molecular part [NH3-(CH2)4-NH3]2+ from left-handed to all-trans conformation and affect noticeably the magnetic properties of the compound. At higher temperature (T = 423 K), a second-order phase transition leading to an orthorhombic phase I (Pncm) is observed by powder X-ray experiments." @default.
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- W2057745729 date "1998-09-01" @default.
- W2057745729 modified "2023-09-23" @default.
- W2057745729 title "Phase transitions in a two-dimensional molecular complex NH3-(CH2)4-NH3CuCl4" @default.
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- W2057745729 doi "https://doi.org/10.1080/01411599808222119" @default.
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