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- W2057754251 abstract "Gaseous mixtures of benzene and ammonia have been passed through a continuous-flow microwave discharge reactor. The principal reaction products were hydrogen cyanide, hydrogen, nitrogen and acetylene. Aniline and butadiene were produced in smaller amounts. At a pressure of 4 × 10−2 bar, no reaction occurred unless the molar ratio of ammonia to benzene exceeded 1 : 1. At 9.3 × 10 −2 bar, no reaction occurred unless the reactant ratio exceeded 2:1. The presence of nickel wire affected the distribution of reaction products. The conversions of benzene were less than those which had previously been found in pure benzene. The maximum conversions of ammonia were much higher than the conversions obtained in pure ammonia. The consumption of both benzene and ammonia were found to be zero order rate processes. The consumption rates of the reactants varied linearly with power absorption in the reactor." @default.
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- W2057754251 date "2007-04-25" @default.
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- W2057754251 title "Reactions of benzene and ammonia in a continuous-flow microwave discharge reactor" @default.
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- W2057754251 doi "https://doi.org/10.1002/jctb.2720241103" @default.
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