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• W2057758753 abstract "The conformational transition of hydrophobically end-capped poly(ethylene oxide), HP-PEO-HP [hydrophobic-poly(ethylene oxide)-hydrophobic], was studied using X-ray diffraction (XRD), differential scanning calorimetry (DSC), and Fourier transform infrared spectroscopy (FTIR) methods. Conformational transitions of HP-PEO-HP from a planar zigzag to a 7/2 helical conformation were observed as the molecular weight of the PEO main chain increased. HP-PEO-HP 1(18), with a PEO molecular weight of 1000 and 18 hydrocarbons on each end, has mainly an α-helical structure in poor solvents, whereas α and β conformations coexist in good solvents. This means that the α-helical structure caused by the hydrogen bonds between the urethane linkages was broken by the high chain mobility caused by the melted adjacent chains of PEO, and instead, the β-sheet was formed by the interaction of multiple hydrogen bonds. Another indication of hydrogen bonds breaking at increasing temperature is the transition of the N−H stretching peak in the FTIR data. HP-PEO-HP 2(18) and 4(18), which have 18 hydrocarbons on each end and PEO molecular weights of 2000 and 4000, respectively, and consist mostly of PEO, showed spherulites. This result also suggests that the PEO molecule has a 7/2 zigzag helical conformation. In contrast, HP-PEO-HP 1(18), which is composed of less PEO than HP-PEO-HP 2(18) and 4(18), did not show a spherulite structure." @default.
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• W2057758753 date "2007-10-24" @default.
• W2057758753 modified "2023-10-17" @default.
• W2057758753 title "Structure Formation of Hydrophobically End-Capped Poly(ethylene oxide) in the Solid State" @default.
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• W2057758753 doi "https://doi.org/10.1021/jp074496j" @default.
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