Matches in SemOpenAlex for { <https://semopenalex.org/work/W2057769314> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2057769314 endingPage "119" @default.
- W2057769314 startingPage "109" @default.
- W2057769314 abstract "Skeletal isomerization of n-hexane and 1-hexene was investigated on molybdenum dioxide MoO2 powder which was gradually reduced under a rapid flow of hydrogen (1 atm) at 350 °C. Significant isomerization was observed with the commercially available MoO2 samples whose overall behavior was qualitatively apparented to the one previously reported of the trioxide MoO3, but not quantitatively. On the other hand, the same experiments conducted with MoO2 prepared in the laboratory showed always negligible isomerization but mainly cracking reactions. The differences between the two sorts of molybdenum dioxide were attributed to the presence in the commercial dioxide of a few percents of Mo6+ oxide—as confirmed by DRX and XPS analysis—whose reduction products are well known to act as very efficient skeletal isomerizing catalysts. Hence, only the results obtained with the purer laboratory made MoO2 are considered to reflect the real properties of this compound. As a consequence, the skeletal isomerizing properties of partially reduced MoO3 powder can hardly be attributed to the molybdenum dioxide MoO2—associated or not with molybdenum metal—which, among other products, is always present in the resulting material." @default.
- W2057769314 created "2016-06-24" @default.
- W2057769314 creator A5025991382 @default.
- W2057769314 creator A5030303786 @default.
- W2057769314 creator A5050225238 @default.
- W2057769314 date "2003-03-01" @default.
- W2057769314 modified "2023-09-28" @default.
- W2057769314 title "Catalytic reactions of n-hexane and 1-hexene on molybdenum dioxide" @default.
- W2057769314 cites W1971545820 @default.
- W2057769314 cites W1976560399 @default.
- W2057769314 cites W2026927191 @default.
- W2057769314 cites W2041813628 @default.
- W2057769314 cites W2050993154 @default.
- W2057769314 cites W2056228361 @default.
- W2057769314 cites W2072549350 @default.
- W2057769314 cites W2085132927 @default.
- W2057769314 cites W2088034291 @default.
- W2057769314 cites W2134137850 @default.
- W2057769314 cites W2298738785 @default.
- W2057769314 cites W2306086324 @default.
- W2057769314 cites W2460770237 @default.
- W2057769314 cites W2913949561 @default.
- W2057769314 cites W74094271 @default.
- W2057769314 doi "https://doi.org/10.1016/s0926-860x(02)00543-4" @default.
- W2057769314 hasPublicationYear "2003" @default.
- W2057769314 type Work @default.
- W2057769314 sameAs 2057769314 @default.
- W2057769314 citedByCount "23" @default.
- W2057769314 countsByYear W20577693142012 @default.
- W2057769314 countsByYear W20577693142013 @default.
- W2057769314 countsByYear W20577693142014 @default.
- W2057769314 countsByYear W20577693142017 @default.
- W2057769314 countsByYear W20577693142019 @default.
- W2057769314 countsByYear W20577693142020 @default.
- W2057769314 countsByYear W20577693142021 @default.
- W2057769314 countsByYear W20577693142023 @default.
- W2057769314 crossrefType "journal-article" @default.
- W2057769314 hasAuthorship W2057769314A5025991382 @default.
- W2057769314 hasAuthorship W2057769314A5030303786 @default.
- W2057769314 hasAuthorship W2057769314A5050225238 @default.
- W2057769314 hasConcept C126661725 @default.
- W2057769314 hasConcept C127413603 @default.
- W2057769314 hasConcept C161790260 @default.
- W2057769314 hasConcept C175708663 @default.
- W2057769314 hasConcept C178790620 @default.
- W2057769314 hasConcept C179104552 @default.
- W2057769314 hasConcept C185592680 @default.
- W2057769314 hasConcept C192562407 @default.
- W2057769314 hasConcept C2777077568 @default.
- W2057769314 hasConcept C2780091738 @default.
- W2057769314 hasConcept C42360764 @default.
- W2057769314 hasConcept C512968161 @default.
- W2057769314 hasConcept C549387045 @default.
- W2057769314 hasConceptScore W2057769314C126661725 @default.
- W2057769314 hasConceptScore W2057769314C127413603 @default.
- W2057769314 hasConceptScore W2057769314C161790260 @default.
- W2057769314 hasConceptScore W2057769314C175708663 @default.
- W2057769314 hasConceptScore W2057769314C178790620 @default.
- W2057769314 hasConceptScore W2057769314C179104552 @default.
- W2057769314 hasConceptScore W2057769314C185592680 @default.
- W2057769314 hasConceptScore W2057769314C192562407 @default.
- W2057769314 hasConceptScore W2057769314C2777077568 @default.
- W2057769314 hasConceptScore W2057769314C2780091738 @default.
- W2057769314 hasConceptScore W2057769314C42360764 @default.
- W2057769314 hasConceptScore W2057769314C512968161 @default.
- W2057769314 hasConceptScore W2057769314C549387045 @default.
- W2057769314 hasIssue "1" @default.
- W2057769314 hasLocation W20577693141 @default.
- W2057769314 hasOpenAccess W2057769314 @default.
- W2057769314 hasPrimaryLocation W20577693141 @default.
- W2057769314 hasRelatedWork W2030407225 @default.
- W2057769314 hasRelatedWork W2041267671 @default.
- W2057769314 hasRelatedWork W2046064739 @default.
- W2057769314 hasRelatedWork W2057769314 @default.
- W2057769314 hasRelatedWork W2065796335 @default.
- W2057769314 hasRelatedWork W2072549350 @default.
- W2057769314 hasRelatedWork W2375824680 @default.
- W2057769314 hasRelatedWork W2505170054 @default.
- W2057769314 hasRelatedWork W2894686292 @default.
- W2057769314 hasRelatedWork W2970941453 @default.
- W2057769314 hasVolume "243" @default.
- W2057769314 isParatext "false" @default.
- W2057769314 isRetracted "false" @default.
- W2057769314 magId "2057769314" @default.
- W2057769314 workType "article" @default.