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- W2057777983 abstract "The kinetics of the oxidation of hydroxylammonium ion by ferricyanide has been investigated at low hydrogen-ion concentrations (pH 4·2–5·7). Reaction occurs by the interaction between ferricyanide and unprotonated hydroxylamine. The radical NH3O·first formed is further oxidised except at low ratios for [Fe(CN)63–]0 : [NH3OH+]0 where it dimerises and subsequently gives the product. The rate law has been obtained as –d//dt[Fe(CN)63–]=k[Fe(CN)63–][NH3OH+][H+]–1 with k= 0·69 × 10–6 l. mole–1 sec.–1 at 25 °C." @default.
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- W2057777983 date "1970-01-01" @default.
- W2057777983 modified "2023-09-23" @default.
- W2057777983 title "Mechanism of the oxidation of hydroxylamine by ferricyanide" @default.
- W2057777983 doi "https://doi.org/10.1039/j19700002060" @default.
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