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- W2057788554 abstract "A new mixed valent molybdenum monophosphate, CsMo6O10(Mo2O7(PO4)4, has been synthesized. It crystallizes in the space groupI42dwitha=9.953(2) A,c=26.413(4) A. Its original three-dimensional framework [Mo8P4O33]∞consists of corner-sharing tetraoctahedral units Mo4O20with the perovskite configuration, ditetrahedral groups Mo2O7, MoO6octahedra, and single PO4tetrahedra. This 3D lattice forms large cages where the Cs+ions are located. An important feature of this structure deals also with the fact that the molybdenum–oxygen framework is itself three-dimensional. The distribution of the electrons in this structure is discussed on the basis of bond valence calculations and magnetic measurements." @default.
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- W2057788554 date "1997-02-01" @default.
- W2057788554 modified "2023-09-25" @default.
- W2057788554 title "A Mixed Valent Molybdenum Monophosphate with an Original Cage Structure CsMo6O10(Mo2O7(PO4)4" @default.
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- W2057788554 doi "https://doi.org/10.1006/jssc.1996.7195" @default.
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