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- W2057788994 abstract "The reaction of o-[1-(alkylthio)alkyl]phenols with silver(I) oxide at room temperature generated o-quinonemethides in good yields along with silver alkanethiolate. This mechanism, based upon one-electron oxidation, is excluded in view of several experimental facts. The resulting o-quinonemethides reacted efficiently with ethyl vinyl ether to afford cis-chromans as the result of endo cycloaddition between (E)-o-quinonemethides and the ether. Similarly, o-[1-(alkylthio)allyl]phenols were converted to cis-chromans via the corresponding (E)-o-quinonemethides (6-allylidenecyclohexadienone). In the absence of dienophiles, some chromenes were obtained from the allylphenols." @default.
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- W2057788994 date "1990-04-01" @default.
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- W2057788994 title "A New Synthesis of<i>o</i>-Quinonemethides and Their Inter- and Intramolecular Cyclization Reactions" @default.
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- W2057788994 doi "https://doi.org/10.1246/bcsj.63.1062" @default.
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