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- W2057860131 abstract "The line shape theory of Hess draws its attractiveness from the fact that it approaches the correct asymptotic theories at low and high pressures. In this paper, Hess’s theory is generalized slightly to describe overlapping lines of diatomic molecules immersed in a bath of diatomic molecules. A ‘‘spherical’’ approximation is introduced in which the collision integrals are averaged over the propagation direction. In terms of a reduced S matrix evaluated in three commonly used coupling schemes, the pressure broadening cross sections agree with well-known results, and the isotropic Dicke line narrowing cross section is expressed in a form suitable for numerical computation. Both cross sections can be expressed as linear sums of generalized cross sections having the same formal structure." @default.
- W2057860131 created "2016-06-24" @default.
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- W2057860131 date "1986-07-15" @default.
- W2057860131 modified "2023-10-12" @default.
- W2057860131 title "Diatomic–diatomic molecular collision integrals for pressure broadening and Dicke narrowing: A generalization of Hess’s theory" @default.
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- W2057860131 doi "https://doi.org/10.1063/1.451277" @default.
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