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- W2057862004 abstract "Hydrocracking reactions of di(1-naphthyl)methane (DNM) and hydrogenated di(1-naphthyl)methanes (H-DNMs) were investigated at 300 °C to examine the relationship between structure and reactivity of the substrates. The results show that in the presence of Ni−S DNM is readily hydrocracked to naphthalene and 1-methylnaphthalene under pressurized hydrogen, while the more deeply DNM is hydrogenated, the more slowly the resulting H-DNMs are hydrocracked. The differences between DNM and H-DNMs and among the different H-DNMs in reactivity toward hydrocracking can be ascribed to the hydrogen-accepting abilities of ipso-carbons in the substrates, the stabilities of leaving arylmethyl radicals and the adsorption strength of the substrates on catalyst surface." @default.
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- W2057862004 date "2002-07-17" @default.
- W2057862004 modified "2023-09-26" @default.
- W2057862004 title "Reactivities of Di(1-naphthyl)methane and Hydrogenated Di(1-naphthyl)methanes toward Hydrocracking over Ni−S" @default.
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- W2057862004 doi "https://doi.org/10.1021/ef0200267" @default.
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