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• W2057871258 endingPage "1849" @default.
• W2057871258 startingPage "1846" @default.
• W2057871258 abstract "Using stereoselective aldol-like condensation as a key methodology, a series of chlorophyll a-based long wavelength cationic chlorins were synthesized using methyl pyropheophorbide a (MPPa) and purpurin-18-N-methoxylimide methyl ester as starting materials. Such long wavelength cationic chlorins possess covalently linked cationic moieties (pyridinium or quinolinium) on the peripheral of their tetrapyrrole macrocycles. It was found that all long wavelength cationic chlorins showed their longest absorption maxima in the range of 712–763 nm, making them potential photosensitizers in photodynamic therapy. The results of preliminary experiments probing in vitro photodynamic effects showed that the purpurinimide derivatives exhibit relatively high phototoxicity in HeLa cells as compared to MPPa derivatives." @default.
• W2057871258 created "2016-06-24" @default.
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• W2057871258 date "2012-03-01" @default.
• W2057871258 modified "2023-09-26" @default.
• W2057871258 title "Synthesis of novel long wavelength cationic chlorins via stereoselective aldol-like condensation" @default.
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• W2057871258 doi "https://doi.org/10.1016/j.bmcl.2012.01.088" @default.
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