FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2057976872> ?p ?o ?g. }

• W2057976872 endingPage "158" @default.
• W2057976872 startingPage "153" @default.
• W2057976872 abstract "The ET spectra of monosubstituted benzenes containing the −OH, −OCH3, −OC(CH3)3, −SH, −SCH3, −SC(CH3)3 and −NHCH3 groups show that in the non-hindered nitrogen and oxygen derivatives the lone pair/π* interaction produces a significant destabilization of the ring 4b1π* MO, while the electron affinity (EA) of the LUMO π* 2a2 is close to that of benzene. The stabilization of the empty π* MOs produced by the sulphur-containing substituents demonstrates the presence of interacting empty orbitals localized at the substituent. The stabilizing effect of these orbitals does not change significantly with the σ framework of the substituent nor with its torsional angle around the S-ring bond. This is consistent with the S 3d character of the stabilizing orbitals. The EA increase of the LUMO in the rotated −SC(CH3)3 derivative is mainly ascribed to the reduced interaction between the S lone-pair orbital and the 4b1 π* MO, and, in part, to σ*/π* interaction." @default.
• W2057976872 created "2016-06-24" @default.
• W2057976872 creator A5013095098 @default.
• W2057976872 creator A5034608772 @default.
• W2057976872 creator A5056804530 @default.
• W2057976872 creator A5068087515 @default.
• W2057976872 date "1983-05-01" @default.
• W2057976872 modified "2023-10-17" @default.
• W2057976872 title "The nature of the stabilizing effect of thio groups on the Π anion states of benzene studied by means of electron transmission spectroscopy" @default.
• W2057976872 cites W1965769649 @default.
• W2057976872 cites W1966936870 @default.
• W2057976872 cites W1968549152 @default.
• W2057976872 cites W1972030092 @default.
• W2057976872 cites W1986114498 @default.
• W2057976872 cites W2016295834 @default.
• W2057976872 cites W2021584170 @default.
• W2057976872 cites W2025241313 @default.
• W2057976872 cites W2033390160 @default.
• W2057976872 cites W2037883546 @default.
• W2057976872 cites W2037898663 @default.
• W2057976872 cites W2039914707 @default.
• W2057976872 cites W2046334198 @default.
• W2057976872 cites W2058771399 @default.
• W2057976872 cites W2068174508 @default.
• W2057976872 cites W2080958810 @default.
• W2057976872 cites W2082090068 @default.
• W2057976872 cites W2086279268 @default.
• W2057976872 cites W2089718304 @default.
• W2057976872 cites W2101184459 @default.
• W2057976872 cites W2138470006 @default.
• W2057976872 cites W2340101573 @default.
• W2057976872 cites W2950090619 @default.
• W2057976872 cites W2950261705 @default.
• W2057976872 cites W2952512834 @default.
• W2057976872 doi "https://doi.org/10.1016/0301-0104(83)85072-1" @default.
• W2057976872 hasPublicationYear "1983" @default.
• W2057976872 type Work @default.
• W2057976872 sameAs 2057976872 @default.
• W2057976872 citedByCount "36" @default.
• W2057976872 crossrefType "journal-article" @default.
• W2057976872 hasAuthorship W2057976872A5013095098 @default.
• W2057976872 hasAuthorship W2057976872A5034608772 @default.
• W2057976872 hasAuthorship W2057976872A5056804530 @default.
• W2057976872 hasAuthorship W2057976872A5068087515 @default.
• W2057976872 hasConcept C121332964 @default.
• W2057976872 hasConcept C14158195 @default.
• W2057976872 hasConcept C147120987 @default.
• W2057976872 hasConcept C147597530 @default.
• W2057976872 hasConcept C155647269 @default.
• W2057976872 hasConcept C178790620 @default.
• W2057976872 hasConcept C185592680 @default.
• W2057976872 hasConcept C189394030 @default.
• W2057976872 hasConcept C2777691172 @default.
• W2057976872 hasConcept C2778689049 @default.
• W2057976872 hasConcept C2780378348 @default.
• W2057976872 hasConcept C2781253882 @default.
• W2057976872 hasConcept C32891209 @default.
• W2057976872 hasConcept C32909587 @default.
• W2057976872 hasConcept C46000676 @default.
• W2057976872 hasConcept C62520636 @default.
• W2057976872 hasConcept C75473681 @default.
• W2057976872 hasConcept C8010536 @default.
• W2057976872 hasConcept C88291069 @default.
• W2057976872 hasConceptScore W2057976872C121332964 @default.
• W2057976872 hasConceptScore W2057976872C14158195 @default.
• W2057976872 hasConceptScore W2057976872C147120987 @default.
• W2057976872 hasConceptScore W2057976872C147597530 @default.
• W2057976872 hasConceptScore W2057976872C155647269 @default.
• W2057976872 hasConceptScore W2057976872C178790620 @default.
• W2057976872 hasConceptScore W2057976872C185592680 @default.
• W2057976872 hasConceptScore W2057976872C189394030 @default.
• W2057976872 hasConceptScore W2057976872C2777691172 @default.
• W2057976872 hasConceptScore W2057976872C2778689049 @default.
• W2057976872 hasConceptScore W2057976872C2780378348 @default.
• W2057976872 hasConceptScore W2057976872C2781253882 @default.
• W2057976872 hasConceptScore W2057976872C32891209 @default.
• W2057976872 hasConceptScore W2057976872C32909587 @default.
• W2057976872 hasConceptScore W2057976872C46000676 @default.
• W2057976872 hasConceptScore W2057976872C62520636 @default.
• W2057976872 hasConceptScore W2057976872C75473681 @default.
• W2057976872 hasConceptScore W2057976872C8010536 @default.
• W2057976872 hasConceptScore W2057976872C88291069 @default.
• W2057976872 hasIssue "1" @default.
• W2057976872 hasLocation W20579768721 @default.
• W2057976872 hasOpenAccess W2057976872 @default.
• W2057976872 hasPrimaryLocation W20579768721 @default.
• W2057976872 hasRelatedWork W1986014900 @default.
• W2057976872 hasRelatedWork W2030950022 @default.
• W2057976872 hasRelatedWork W2035662849 @default.
• W2057976872 hasRelatedWork W2055787245 @default.
• W2057976872 hasRelatedWork W2170631982 @default.
• W2057976872 hasRelatedWork W2211342729 @default.
• W2057976872 hasRelatedWork W2778405304 @default.
• W2057976872 hasRelatedWork W2949443483 @default.
• W2057976872 hasRelatedWork W3015795223 @default.
• W2057976872 hasRelatedWork W4220978838 @default.
• W2057976872 hasVolume "77" @default.
• W2057976872 isParatext "false" @default.

• next