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- W2058004806 abstract "The thermal- and photon-induced phase transitions of [Fe(2-pic) 3 ]Cl 2 EtOH from a high-spin (HS) state ( S = 2) to a low-spin (LS) state ( S = 0) were observed by X-ray Emission Spectroscopy (XES) and X-ray Absorption Spectroscopy (XAS). The spin state was observed with Fe 3p-1s XES from the HS and photon-induced (PI) phase took S = 2 and LS state took S = 0. Each spectrum of the decay process from the PI phase to the LS state could be described with the superposition of those of the HS and LS states. In XAS, a different spectrum was also observed in the HS and LS states, and likewise by XES; the difference in the pre-edge structure between the HS and LS states was explained based on the difference of Fe unoccupied 3d partial density of state calculated by the DV-X f method." @default.
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- W2058004806 date "2002-01-01" @default.
- W2058004806 modified "2023-10-03" @default.
- W2058004806 title "Spin-State Transitions in an Iron Spin-Crossover Complex Observed with X-ray Emission and X-ray Absorption" @default.
- W2058004806 doi "https://doi.org/10.1080/01411590290034065" @default.
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