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- W2058009076 abstract "A novel zinc phthalocyanine containing four 17-crown-5 ether voids(17C5ZnPc) has been synthesized and characterized. UV-visible absorption and fluorescence emission spectra and as sociated photophysical parameters have been determined. In contrast to most of the crown ether substituted phthalocyanines, no cofacial dimer formation is observed in the presence of alkali metal salts. In addition to the fluorescence at 710 nm from S1, a strong upper excited state (Soret S2) emission around 424 nm has been detected for the first time in the phthalocyanine series. Fluorescence decay of S1 and S2 emission can be analyzed by mono- and biexponential fits respectively. X-ray structure analysis showed that the crown ether unit is conformationally deformed and oblate that may account for the unusual spectroscopic properties." @default.
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- W2058009076 date "2010-08-27" @default.
- W2058009076 modified "2023-09-26" @default.
- W2058009076 title "Synthesis and spectroscopic properties of a novel zinc phthalocyanine with four 17-membered crown ether voids" @default.
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- W2058009076 doi "https://doi.org/10.1002/cjoc.19970150510" @default.
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