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- W2058023523 abstract "An investigation is reported on the homologation of alk-1-ynes to allenes by the cuprous bromide-catalyzed reaction with formaldehyde and di-isopropylamine, including extension to an aromatic acetylene and a diacetylene. Optimization of yields was studied. A mechanism is proposed involving an intermediate hydrido-cuprate species derived from a 1:1 Mannich base–cuprous bromide π-complex. The mechanism is supported by labelling experiments and observed substituent effects." @default.
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- W2058023523 date "1984-01-01" @default.
- W2058023523 modified "2023-10-08" @default.
- W2058023523 title "Observation on the synthesis of allenes by homologation of alk-1-ynes" @default.
- W2058023523 doi "https://doi.org/10.1039/p19840000747" @default.
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