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- W2058032374 abstract "Abstract C5Me5Rh(L)P2Me4 (L = CO, C2H4) reacts with [C5Me5Rh(μ-CO)]2, to give the trinuclear complexes C5Me5(L)Rh(μ-P2Me4)RhC5Me5(μ-CO)2RhC5Me5 (VI, VII). In the reactions of C5Me5Rh(CO)P2Me4 with C5H5(CO)2 (M = Rh, Co) and C5H4RMn(CO)3 (R = H, Me), the homo- and hetero-metallic binuclear compounds C5Me5(CO)Rh(μ-P2Me4)M(CO)C5H5 (VIII, IX) and C5Me5(CO)Rh(μ-P2Me4)Mn(CO)2C5H4R (X, XI) are obtained in almost quantitative yield. The X-ray structure of the complex C5Me5[P(OMe)3]Rh(μ-CO)2RhC5Me5 (III), which is structurally related to VI and VII, has been determined. The molecule contains an unsymmetrical, non-planar Rh2C2-skeleton with different Rh-C(O) bond lengths. The Rh-Rh distance is 268.5(1) pm; the planes of the two five-membered rings form an angle of 62.6°." @default.
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- W2058032374 date "1984-04-01" @default.
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- W2058032374 title "Dreikern- sowie homo- und heterometall-zweikernkomplexe mit der baueinheit C5Me5Rh. Die kristallstruktur von C5Me5[P(OMe)3[Rh(μ-CO)2RhC5Me5" @default.
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- W2058032374 doi "https://doi.org/10.1016/0022-328x(84)80114-x" @default.
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