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• W2058052080 startingPage "2401" @default.
• W2058052080 abstract "Efficient and high yielding stereoselective assembly of the tetrasaccharyl cap region of the lipophosphoglycan from the protozoan parasite Leishmania using the n-pentenyl glycoside protocol is described in this paper. Both convergent and linear syntheses lead to the protected tetrasaccharide 14; however, the convergent assembly is more efficient in terms of product recovery. Regioselective reductive cleavage of benzylidene acetal 4 with triethylsilane−trifluoroacetic acid system liberates the required C-4 OH in excellent yield, without affecting the resident chloroacetate functionality." @default.
• W2058052080 created "2016-06-24" @default.
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• W2058052080 date "1996-01-01" @default.
• W2058052080 modified "2023-10-12" @default.
• W2058052080 title "<i>n</i>-Pentenyl Glycoside Methodology in the Stereoselective Construction of the Tetrasaccharyl Cap Portion of <i>Leishmania</i> Lipophosphoglycan" @default.
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• W2058052080 doi "https://doi.org/10.1021/jo9520102" @default.
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