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- W2058072766 abstract "Two series of new wholly aromatic copolyesters were prepared from 6-hydroxy-5-phenyl-2-naphthoic acid (HPNA) and 4-hydroxybenzoic acid (HBA), and 4'-hydroxy-3'-phenylbiphenyl-4-carboxylic acid (HPBA) and 4-hydroxybenzoic acid in varying mole ratio. The polyesters were synthesized in melts using the acetylated monomers. They were characterized for their crystallinity, liquid crystallinity, thermal transitions and thermal stability by wide-angle X-ray diffractometry, differential scanning calorimetry, thermogravimetry and on a polarizing microscope. In general, the HPNA copolyesters revealed higher degree of crystal-Unities and greater melting temperatures than the HPBA copolyesters. This difference is explained by the planar geometry of naphthalene moiety in the HPNA structure. In contrast, the two phenylene rings of the HPBA unit along the backbone may not be coplanar. All of the polyesters appear to be thermotropic." @default.
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- W2058072766 date "1995-06-01" @default.
- W2058072766 modified "2023-10-16" @default.
- W2058072766 title "Wholly aromatic polyesters derived from 6-hydroxy-5-phenyl-2-naphthoic acid and 4'-hydroxy-3′ -phenylbiphenyl-4-carboxylic acid" @default.
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- W2058072766 doi "https://doi.org/10.1002/masy.19950960110" @default.
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