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• W2058114705 endingPage "12225" @default.
• W2058114705 startingPage "12216" @default.
• W2058114705 abstract "A novel class of resorcinarene-based cavitands 2a−e that fold into a deep (8 × 10 Å dimensions) open-ended cavity by means of intramolecular hydrogen bonds has been synthesized. As follows from the FTIR and 1H NMR spectral data in apolar solvent, a seam of eight intramolecular hydrogen bonds is stitched along the upper rim of the structure 2a−e; the amide CO...H−N interactions bridge adjacent ringsinterannular bindingand are held in place by the seven-membered intraannular hydrogen bonds. The self-folding in 2a−e is reversibly controlled by solvent and temperature. Complexation of self-folding cavitands 2a−e with organic molecules such as (1-substituted) adamantanes, lactams, and cyclohexane derivatives was demonstrated by 1H NMR spectroscopy in CDCl3, benzene-d6 and p-xylene-d10; the binding energy -ΔG° values of 2−4 kcal mol-1 in p-xylene-d10 at 295 K were calculated. The exchange between complexed and free guest species is slow on the NMR time-scale, and it is proposed that hydrogen bonds are responsible for these unique features. Employing the pronounced upfield 1H NMR shifts of the complexed guest molecules, attempts were made to study the structure of the caviplexes “from inside”, and the orientation of the encapsulated adamantanes 12,13, as well as noncovalent interactions of complexed ε-caprolactam 9b with the host walls were deduced. Even though the guest-exchange process in 2a−e is slow on the NMR time scale (k = 2 ± 1 s-1), it is still faster than that observed for the completely closed hydrogen-bonded calixarene-based capsules or for covalently sealed hemicarceplexes. This places them in an unusual position in the scale of cavity-containing receptors and opens new perspectives to use 2a−e in catalysis and as 1H NMR supramolecular shift reagents." @default.
• W2058114705 created "2016-06-24" @default.
• W2058114705 creator A5004784794 @default.
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• W2058114705 date "1998-11-12" @default.
• W2058114705 modified "2023-10-16" @default.
• W2058114705 title "Self-Folding Cavitands" @default.
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• W2058114705 doi "https://doi.org/10.1021/ja982970g" @default.
• W2058114705 hasPublicationYear "1998" @default.
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