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- W2058118929 abstract "The effect of temperature on the polarization resistance (Rp) has been analyzed for a corrosion reaction in which both the anodic and cathodic half-reactions are under pure activation control, e.g. the corrosion of iron in 1 N H2SO4. The analysis was performed in terms of the Stern-Geary equation: Rp was related to temperature by the equation Rp(T) = T/298 Rp (289) exp (E∗/R(1/T − 1/298)] where Rp(T) and Rp(298) are the values of polarization resistance at temperatures T and 298 K, respectively and E∗ is the activation energy of the corrosion reaction. The polarization resistance was measured at different temperatures in presence of varying concentrations of three inhibitors, namely thiourea (TU), thiosemicarbazide (TSC) and thioacetamide (TA). The polarization resistance decreased with increase in temperature or decrease in inhibitor concentration. The experimental results followed the above equation satisfactorily; the value of E∗ was found to be dependent on the type of inhibitor rather than on its concentration. The mean values of E∗ are 60.3, 59.4, 47.6 and 33.5 kJ mol−1 in the blank, TSC, TA and TU solutions, respectively. The mechanism of inhibition was discussed in the light of these results." @default.
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- W2058118929 date "1986-01-01" @default.
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- W2058118929 title "The effect of temperature on the polarization resistance — I. Activation control" @default.
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- W2058118929 doi "https://doi.org/10.1016/0010-938x(86)90137-x" @default.
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