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- W2058127863 abstract "Infra-red spectra and X-ray diagrams of polyoxymethylene samples prepared in various ways, of trioxanedioxolane copolymers and of a polyoxymethylene-polydioxolane blend were obtained. With hexagonal crystalline polyoxymethylene (HCPOM), it is possible to prepare two forms, A and B, differing in their infrared spectra; with copolymers, the maximum attainable content of form A rapidly decreases with increasing content of oxyethylene units in the chain. Form A could not be prepared in the polyoxymethylene-polydioxolane blend. Infra-red spectra of the two forms, A and B, of HCPOM differ in the vibrational interactions of neighbouring chains; these interactions are large in form A and small in form B. The possible structures of the A and B forms of HCPOM are discussed." @default.
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- W2058127863 date "1987-02-01" @default.
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- W2058127863 title "Structural modifications of hexagonal crystalline polyoxymethylene. Infra-red and X-ray study" @default.
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- W2058127863 doi "https://doi.org/10.1016/0032-3861(87)90407-1" @default.
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