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- W2058163905 abstract "A rigorous theory of the polarographic kinetic currents, which is valid without limitation in the magnitude of the relevant rate constant, is developed for the first-order preceding chemical reaction proceeding at the expanding plane electrode. The simple, approximate equations with reasonable accuracy are presented for the instantaneous and average values of kinetic currents. They hold within maximum error of 2–3%, provided that the height of the kinetic current is larger than about one-tenth of the corresponding diffusion current. For the catalytic currents, on the other hand, on the basis of the numerical tables given by Koutecký and Henke and Hans simple algebraic expressions are also presented for the instantaneous and average currents, which hold within less than 1% error." @default.
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- W2058163905 date "1974-04-01" @default.
- W2058163905 modified "2023-10-16" @default.
- W2058163905 title "Contributions to the theory of kinetic and catalytic currents in polarography" @default.
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- W2058163905 doi "https://doi.org/10.1016/s0022-0728(74)80245-7" @default.
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