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- W2058166695 abstract "The purpose of this paper is to examine the behaviour of ammonia vapour which has escaped to the atmosphere as a result of the accidental failure of a pressurized container. It is shown that the circumstances of the release are such that the formation of a cold ammonia air mixture, which is denser than the surrounding air, is likely. As a result, gravity driven phenomena must be taken into account; the cloud slumps and becomes very broad. It is shown that this slumping is insensitive to assumptions made about the rate of entrainment of the air and about the rate at which the mixture is heated by the ground. It is also demonstrated that, unless the windspeed is exceedingly low, the dispersing ammonia may not become buoyant; this is another phenomenon that is insensitive to parameter variations. A section of the paper is devoted to a critical examination of the uncertainties which must be overcome before a complete model of the escape of ammonia from a pressurized container can be written down. It is argued, however, that the characteristic features described above are not sensitive to these uncertainties. Finally, a simple model is used to describe the behaviour of a 20 Te “puff” of ammonia and the results are compared with accounts of accidental escapes of about that size. It is demonstrated that agreement with such facts as can be established is satisfactory." @default.
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- W2058166695 date "1978-01-01" @default.
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- W2058166695 title "Releases of anhydrous ammonia from pressurized containers — the importance of denser-than-air mixtures" @default.
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- W2058166695 doi "https://doi.org/10.1016/0004-6981(78)90269-x" @default.
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