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- W2058183833 abstract "The electrochemical reduction of a cell growth inhibitor, ammonium 5-bromo-2′deoxyuridine-5′-methylphosphate (BrdUrdOPO2Me), was investigated in order to compare its electrochemical properties with those of 5-bromo-2′-deoxyuridine (BrdUrd) and of 5-bromo-2′-deoxyuridine-5′-phosphate (BrdUMP). The derivatives f BrdUrd differ markedly in their electrochemical behavior from BrdUrd because of the influence of the methylphosphonate or phosphate groups. Current vs pH plots for BrdUrdOPO2Me and BrdUMP decrease in the form of an acid dissociation curve and assume kinetic behaviour at high pH values. Controlled potential electrolysis at a stirred mercury cathode of BrdUrdOPO2Me requires two electrons per mole. Autoradiochromatographic analysis of the electrolytic product of the tritium labeled ammoniumbromodeoxyuridine-5′-methyl[3H]phosphate shows that the methylphosphonate group remains intact during the course of the electrolysis. Electrolysis results in debromination and the product exhibits an uv spectrum identical to a 2′-deoxyuridine derivative." @default.
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- W2058183833 date "1978-05-01" @default.
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- W2058183833 title "Electrochemical reduction of ammonium 5-bromo-2′-deoxyuridine-5′-methylphosphonate: an inhibitor of cell growth" @default.
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- W2058183833 doi "https://doi.org/10.1016/0013-4686(78)87048-0" @default.
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