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- W2058249281 abstract "Chemical fixation of carbon dioxide to cyclic carbonates proceeds effectively under extremely mild temperature and pressure by using a bifunctional nucleophile–electrophile catalyst system of tetradentate Schiff-base aluminum complexes ((Salen)AlX) in conjunction with a quaternary ammonium salt (n-Bu4NY) in the absence of any organic solvent. Electrophilicity of central Al3+ ion and the steric factor of substituent groups on the aromatic rings of (Salen)AlX (electrophile), and nucleophilicity and leaving ability of the anion Y− of n-Bu4NY (nucleophile) have a great effect on the catalytic activity of the bifunctional catalyst." @default.
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- W2058249281 date "2004-03-01" @default.
- W2058249281 modified "2023-10-17" @default.
- W2058249281 title "Chemical fixation of carbon dioxide to cyclic carbonates under extremely mild conditions with highly active bifunctional catalysts" @default.
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- W2058249281 doi "https://doi.org/10.1016/j.molcata.2003.09.010" @default.
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