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• W2058252512 abstract "This paper reports the application of a new general tool for the study of multicenter bonding, namely the so-called generalized population analysis, to the investigation of interesting geometry dependent variation of 3c-2e bonding in the (C···H···C) fragments of ingeniously designed organic cations I and II. This phenomenon was previously characterized by the correlation between experimental 1H NMR chemical shifts of the central hydrogen in the (C···H···C) fragment and the changes in the corresponding C−H−C bond angle. The observed values of both chemical shifts and C−H−C angles are shown herein to correlate with the calculated 3-center bond indices but the dependence displays splitting into two separate lines according to the type of corresponding cation." @default.
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• W2058252512 date "2004-03-20" @default.
• W2058252512 modified "2023-10-12" @default.
• W2058252512 title "Multicenter Bonding in Organic Chemistry. Geometry-Sensitive 3c-2e Bonding in (C···H···C) Fragments of Organic Cations" @default.
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• W2058252512 doi "https://doi.org/10.1021/jo035506p" @default.
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