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• W2058273804 abstract "Highly active and stable electrocatalysts for the reduction of nitrate ions were prepared by the adsorption of PdCl42− ions onto a tin monolayer on Au(1 1 1) followed by reduction of the adsorbed PdCl42−. The maximum atomic ratio of Pd to Sn, and hence the surface Au, determined using a quartz crystal microbalance, X-ray photoelectron spectroscopy and cyclic voltammetry, was 0.87, which corresponds to 0.3 μg-Pd cm−2. Despite such an extremely low loading of Pd, the Pd/Sn/Au electrodes showed high electrocatalytic activity (−3.5 mA cm−2 at −0.1 V vs. Ag∣AgCl) and N2 selectivity (37%), both of which are comparable to the highest values reported at different electrodes. In addition, the reduction current on the Pd/Sn/Au electrodes remained constant for hours and decreased only due to the exhaustion of nitrate ions in solution." @default.
• W2058273804 created "2016-06-24" @default.
• W2058273804 creator A5001571942 @default.
• W2058273804 creator A5044530239 @default.
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• W2058273804 date "2004-10-01" @default.
• W2058273804 modified "2023-10-18" @default.
• W2058273804 title "High electrocatalytic performance of Pd/Sn/Au electrodes for nitrate reduction" @default.
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• W2058273804 doi "https://doi.org/10.1016/j.jelechem.2004.06.004" @default.
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