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- W2058282913 abstract "The infrared spectra of several square planar cis and trans palladium (II) and platinum (II) pyridine complexes of the type MPy2X2 (where X = Cl, Br and I) have been recorded from 2000 to 50 cm−1. Comparison of the spectra of complexed pyridine to that of the free base shows nine normal vibrations have shifted to higher frequencies on the order of fifteen to eighty wavenumbers. The shifts are attributed to changes in the electron density over the pyridine ring. Only insignificant shifts in a few of the normal modes of the complexed pyridine were observed between the corresponding cis and trans isomers. The assigmnent of the MX stretching and bending vibrations as well as possible assignments for the MN stretching vibrations are given and discussed. The infrared spectra of palladium (II) 2,2-Bipyridyl complexes of the type Pd(Bipy)2X2 (where X = Cl, Br and I) have also recorded from 2000 to 50 cm−1. Comparison of the spectra to those of the pyridine complexes and the free bipyridine is made." @default.
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- W2058282913 date "1967-04-01" @default.
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- W2058282913 title "Far infrared spectra of palladium compounds—II Pyridine and 2,2′-bipyridyl complexes of palladium (II) and platinum (II)" @default.
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- W2058282913 doi "https://doi.org/10.1016/0584-8539(67)80035-7" @default.
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