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- W2058283375 abstract "A uniform view of electronic degeneracies, resulting from finite point group symmetries, is developed. It relates any n-fold degeneracy to the geometrical structure formed by the set of equidistant points in a space with exactly n dimensions. Jahn-Teller interactions within the degenerate manifold can simply be represented as bond stretchings of this structure. This approach thus can be qualified as the chemical perspective to the study of vibronic instabilities. The procedure is described for two-fold, three-fold, four-fold, and five-fold degeneracies. As a result a simple general proof of the Jahn-Teller theorem can be obtained. The electronic degeneracy is connected to the reaction graph of the stable minima on the surrounding Jahn-Teller surface. The findings are illustrated with some structural and dynamic molecular examples." @default.
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- W2058283375 date "2007-01-01" @default.
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- W2058283375 title "The Jahn–Teller Effect in Chemistry" @default.
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