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- W2058304178 abstract "Der Ketoester 13 cyclisiert unter aprotischen Bedingungen bevorzugt zum 1,2-cis-Hydroxyester 16, der zu 17 gespalten wird. Hydroxylierung von 17 durch Bromierung und Solvolyse fuhrt zum Nogalamycin-Aglycon 19 mit 2,4-trans-Hydroxygruppen.Synthetic Anthracyclinones, 35. – Synthesis of the Nogalamycin AglyconThe keto ester 13 is predominantly cyclized to the 1,2-cis-hydroxy ester 16 under aprotic conditions. Dimethyl ether 16 is split to 17. Hydroxylation of 17 by bromination and hydrolysis affords the nogalamycin aglycon 19 with 2,4-trans-hydroxy groups." @default.
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- W2058304178 date "1987-12-16" @default.
- W2058304178 modified "2023-10-01" @default.
- W2058304178 title "Synthetische Anthracyclinone, 35. Synthese des Nogalamycin-Aglycons" @default.
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- W2058304178 doi "https://doi.org/10.1002/jlac.198719870870" @default.
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