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- W2058357330 abstract "Abstract Stability relations between the three polymorphs for Co2SiO4 (olivine, modified spinel and spinel) are studied by the comparison of the thermodynamical properties on the basis of their precise crystal structures and the experimental results for synthesis. In spite of violation of the Pauling's electrostatic valency rule, the modified spinel structure is not necessarily unstable with respect to the other polymorphs. The gradients of the transition curves in the P-T diagram and the molar volumes indicate that entropy becomes smaller in the order of olivine, modified spinel, and spinel. These entropy changes between the three polymorphs are qualitatively explained by the modes of connection of the chains of coordination polyhedra within each polymorph." @default.
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- W2058357330 date "1972-02-01" @default.
- W2058357330 modified "2023-10-03" @default.
- W2058357330 title "Stability relations between olivine, spinel and modified spinel" @default.
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- W2058357330 doi "https://doi.org/10.1016/0012-821x(72)90080-5" @default.
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