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- W2058364336 abstract "The thermodynamics of the α,β and γ polymorphs of AlH3 were determined using differential scanning calorimetry and ex situ X-ray diffraction. These results demonstrate that at around 100 ° C the decomposition of the β and γ polymorphs occurs by an initial phase transition to the α polymorph followed by decomposition of the α phase. The total heat evolved during the β→α transition is 1.5±0.4 kJ/mol AlH3 and 2.8±0.4 kJ/mol AlH3 during the γ→α transition. The transformation to the α phase is exothermic and is therefore likely to occur spontaneously at room temperature. A formation enthalpy of approximately −10 kJ/mol AlH3 was measured for α-AlH3, which is in good agreement with previous experimental and calculated results." @default.
- W2058364336 created "2016-06-24" @default.
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- W2058364336 date "2006-11-01" @default.
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- W2058364336 title "Thermodynamics of the <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si1.gif overflow=scroll><mml:mstyle mathvariant=normal><mml:mi>α</mml:mi></mml:mstyle><mml:mtext>,</mml:mtext><mml:mstyle mathvariant=normal><mml:mi>β</mml:mi></mml:mstyle></mml:math> and <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si2.gif overflow=scroll><mml:mstyle mathvariant=normal><mml:mi>γ</mml:mi></mml:mstyle></mml:math> polymorphs of AlH3" @default.
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- W2058364336 doi "https://doi.org/10.1016/j.jallcom.2005.11.086" @default.
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