FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2058396093> ?p ?o ?g. }

• W2058396093 endingPage "212" @default.
• W2058396093 startingPage "204" @default.
• W2058396093 abstract "X-ray photoelectron spectroscopy (XPS, ESCA) was used to determine the tungsten oxidation states in a 5 wt.% WO3/TiO2 catalyst reduced in hydrogen in the temperature range 400–700°C. Because, in the region of interest, W 4f overlaps with the Ti 3p energy level, a multiple analysis procedure including deconvolution, non-linear leastsquares curve fitting and factor analysis was used to analyze the data. Deconvolution was better able to resolve the peaks in the W 4f region and thus elucidate the positions of the tungsten components for each reduction temperature. It was shown that there is a maximum of three W 4f doublets. The W 4f7/2 peaks of these components were located at 35.5, 33.3 and 31.1 eV and they were assigned to W+6, W+4 and Wo, respectively. Factor analysis verified the presence of three spectral tungsten components. X-ray diffraction verified the presence of Wo on reduction at 675°C. Non-linear least-squares curve fitting, using the positions from deconvolution, was able to determine the distribution of tungsten oxidation states as a function of reduction temperature: W+6 steadily decreased with increasing reduction temperature, W+4 initially appears at 408°C and goes through a maximum around 580°C; Wo was first detected following reduction at 550°C and was the only species present for reduction temperatures higher than 665°C. From the distribution, it is proposed that, unlike the molybdenum systems, tungsten undergoes a more simplified reduction process in which only one intermediate oxidation state (presumably W+4) is detected." @default.
• W2058396093 created "2016-06-24" @default.
• W2058396093 creator A5003689289 @default.
• W2058396093 creator A5023324383 @default.
• W2058396093 creator A5047411066 @default.
• W2058396093 creator A5087248115 @default.
• W2058396093 date "1995-04-01" @default.
• W2058396093 modified "2023-10-16" @default.
• W2058396093 title "Study of the reduction behavior of W/TiO2 catalysts by XPS using curve fitting, deconvolution and factor analysis" @default.
• W2058396093 cites W1965129965 @default.
• W2058396093 cites W1966129969 @default.
• W2058396093 cites W1970068798 @default.
• W2058396093 cites W1975895111 @default.
• W2058396093 cites W1978395518 @default.
• W2058396093 cites W1987152514 @default.
• W2058396093 cites W1992214743 @default.
• W2058396093 cites W1994966506 @default.
• W2058396093 cites W1998295922 @default.
• W2058396093 cites W1999991586 @default.
• W2058396093 cites W2000883834 @default.
• W2058396093 cites W2001636298 @default.
• W2058396093 cites W2011812211 @default.
• W2058396093 cites W2039524370 @default.
• W2058396093 cites W2040083783 @default.
• W2058396093 cites W2043841466 @default.
• W2058396093 cites W2045080302 @default.
• W2058396093 cites W2066390215 @default.
• W2058396093 cites W2079316932 @default.
• W2058396093 cites W2086688825 @default.
• W2058396093 cites W2087941240 @default.
• W2058396093 cites W2102067522 @default.
• W2058396093 cites W2121203842 @default.
• W2058396093 cites W2162870748 @default.
• W2058396093 cites W2949627010 @default.
• W2058396093 cites W4238517388 @default.
• W2058396093 cites W4255318587 @default.
• W2058396093 cites W7166526 @default.
• W2058396093 doi "https://doi.org/10.1002/sia.740230403" @default.
• W2058396093 hasPublicationYear "1995" @default.
• W2058396093 type Work @default.
• W2058396093 sameAs 2058396093 @default.
• W2058396093 citedByCount "24" @default.
• W2058396093 countsByYear W20583960932012 @default.
• W2058396093 countsByYear W20583960932014 @default.
• W2058396093 countsByYear W20583960932015 @default.
• W2058396093 countsByYear W20583960932017 @default.
• W2058396093 countsByYear W20583960932020 @default.
• W2058396093 countsByYear W20583960932023 @default.
• W2058396093 crossrefType "journal-article" @default.
• W2058396093 hasAuthorship W2058396093A5003689289 @default.
• W2058396093 hasAuthorship W2058396093A5023324383 @default.
• W2058396093 hasAuthorship W2058396093A5047411066 @default.
• W2058396093 hasAuthorship W2058396093A5087248115 @default.
• W2058396093 hasConcept C105795698 @default.
• W2058396093 hasConcept C113196181 @default.
• W2058396093 hasConcept C120665830 @default.
• W2058396093 hasConcept C121332964 @default.
• W2058396093 hasConcept C1276947 @default.
• W2058396093 hasConcept C174576160 @default.
• W2058396093 hasConcept C175708663 @default.
• W2058396093 hasConcept C178790620 @default.
• W2058396093 hasConcept C179104552 @default.
• W2058396093 hasConcept C184389593 @default.
• W2058396093 hasConcept C185592680 @default.
• W2058396093 hasConcept C33923547 @default.
• W2058396093 hasConcept C43617362 @default.
• W2058396093 hasConcept C46141821 @default.
• W2058396093 hasConcept C4839761 @default.
• W2058396093 hasConcept C542268612 @default.
• W2058396093 hasConcept C549387045 @default.
• W2058396093 hasConceptScore W2058396093C105795698 @default.
• W2058396093 hasConceptScore W2058396093C113196181 @default.
• W2058396093 hasConceptScore W2058396093C120665830 @default.
• W2058396093 hasConceptScore W2058396093C121332964 @default.
• W2058396093 hasConceptScore W2058396093C1276947 @default.
• W2058396093 hasConceptScore W2058396093C174576160 @default.
• W2058396093 hasConceptScore W2058396093C175708663 @default.
• W2058396093 hasConceptScore W2058396093C178790620 @default.
• W2058396093 hasConceptScore W2058396093C179104552 @default.
• W2058396093 hasConceptScore W2058396093C184389593 @default.
• W2058396093 hasConceptScore W2058396093C185592680 @default.
• W2058396093 hasConceptScore W2058396093C33923547 @default.
• W2058396093 hasConceptScore W2058396093C43617362 @default.
• W2058396093 hasConceptScore W2058396093C46141821 @default.
• W2058396093 hasConceptScore W2058396093C4839761 @default.
• W2058396093 hasConceptScore W2058396093C542268612 @default.
• W2058396093 hasConceptScore W2058396093C549387045 @default.
• W2058396093 hasIssue "4" @default.
• W2058396093 hasLocation W20583960931 @default.
• W2058396093 hasOpenAccess W2058396093 @default.
• W2058396093 hasPrimaryLocation W20583960931 @default.
• W2058396093 hasRelatedWork W1990866792 @default.
• W2058396093 hasRelatedWork W1993620050 @default.
• W2058396093 hasRelatedWork W2014092843 @default.
• W2058396093 hasRelatedWork W2075152053 @default.
• W2058396093 hasRelatedWork W2102105826 @default.
• W2058396093 hasRelatedWork W2105804409 @default.
• W2058396093 hasRelatedWork W2107588191 @default.

• next