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- W2058427009 abstract "In the first part of this paper the various mechanisms are discussed by which the forbidden transitions in the incomplete 4f-shell can occur. This discussion is based on a paper by Van Vleck, but the estimated intensities do not in all respects agree with those of that paper. It is shown that the electric quadiupole radiation is far too weak to account for the observed intensities, whereas the magnetic dipole radiation only under certain circumstances will be able to do so. In the second part a few experimental results on this subject are surveyed and discussed. Some instances of magnetic dipole radiation are explained with the rules derived in part I, some others are predicted. It is shown that the electric dipole radiation as a rule may account for intensities of the required order, except for two strong bands in Pr+++ and Tm+++, which are difficult to explain on the basis of the discussed mechanisms." @default.
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- W2058427009 date "1945-12-01" @default.
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- W2058427009 title "On the intensities and the multipole character in the spectra of the rare earth ions" @default.
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- W2058427009 doi "https://doi.org/10.1016/s0031-8914(45)80009-5" @default.
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